Abstract A novel, manganese-catalyzed oxidative azidation of cyclobutanols is described. A wide range of primary, secondary, and tertiary alkyl azides were generated in synthetically useful yields and exclusive regioselectivity. Aside from linear alkyl azides, otherwise elusive medium-sized cyclic azides were also readily prepared.
Alkane can be produced from alkyl halides predominantly by two ways: Alkanes can be prepared from alkyl halides (except fluorides) through reduction with zinc and dilute hydrochloric acid. CH3-Cl + H2 → CH4 + HCl. 2. Wurtz reaction: In dry ethereal solution, on treating alkyl halides with sodium metal, production of alkanes is higher. Đọc thêm
a accessing valuable (amino)alkylated arenes via anti-markovnikov hydro (amino)alkylation of simple styrene derivatives. b biologically active molecules containing (γ-amino) alkylated arenes. c...
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a, reported acid-catalysed hydrohalogenation of terminal alkenes for the synthesis of branched alkyl halides. b, reported halogen radical addition to terminal alkenes for the …
A series of carbazole amide derivatives were synthesized by adjusting the n-alkyl chain with different lengths from methyl to octyl (CAC-N, N = 1–8). Their photophysical behaviors were highly dependent on the parity of their alkyl chain. That is, compounds with even-numbered alkyl chains exhibited efficient Journal of Materials Chemistry C HOT Papers
5-ETHYL-4-METHYL-1H-IMIDAZOL-2-AMINE TERT-BUTYL (3- (PYRIDIN-2-YL)-1,2,4-OXADIAZOL-5-YL)METHYLCARBAMATE 2- (4-ISOPENTYL-1H-1,2,3-TRIAZOL-1-YL)ETHAN-1-AMINE 6- ( (4-ETHYLPIPERAZIN-1-YL)METHYL)NICOTINIC ACID 4-AMINO-1-BENZYL-2 (1H)-PYRIMIDINONE METHOXY (4-METHYLPHENYL)ACETIC ACID …
5-ETHYL-4-METHYL-1H-IMIDAZOL-2-AMINE TERT-BUTYL (3- (PYRIDIN-2-YL)-1,2,4-OXADIAZOL-5-YL)METHYLCARBAMATE 2- (4-ISOPENTYL-1H-1,2,3-TRIAZOL-1 …
Alkane can be produced from alkyl halides predominantly by two ways: Alkanes can be prepared from alkyl halides (except fluorides) through reduction with zinc and dilute hydrochloric acid. CH3-Cl + H2 → CH4 + HCl. 2. Wurtz reaction: In dry ethereal solution, on treating alkyl halides with sodium metal, production of alkanes is higher. Đọc ...
a, reported acid-catalysed hydrohalogenation of terminal alkenes for the synthesis of branched alkyl halides. b, reported halogen radical addition to terminal alkenes for the synthesis of linear...
Cu‐Catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO To Provide One‐Carbon‐Extended Alcohols - Zhao - 2018 - Angewandte Chemie International Edition - Wiley Online Library Angewandte Chemie International Edition Communication Cu-Catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO To Provide One-Carbon-Extended …
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a accessing valuable (amino)alkylated arenes via anti-markovnikov hydro (amino)alkylation of simple styrene derivatives. b biologically active molecules containing (γ …
Currently, the hydrogenolysis of aromatic C-O bonds requires heterogeneous catalysts that operate at high temperature and pressure and lead to a mixture of products from competing hydrogenolysis of aliphatic C-O bonds and hydrogenation of the arene.
In the broad field of organic semiconductor, it is also found that the length and the branching position of the alkyl chain can affect the crystal structure and molecular packing in …
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Alkane can be produced from alkyl halides predominantly by two ways: Alkanes can be prepared from alkyl halides (except fluorides) through reduction with zinc and dilute hydrochloric acid. …
In the broad field of organic semiconductor, it is also found that the length and the branching position of the alkyl chain can affect the crystal structure and molecular packing in the solid state, so that changes the small molecule's electronic property.33, 34, 35, 36 Since the orientation of alkyl chains in Y6 is quite different from the previously reported high …
The grafting efficiency of QA-alkyl can be calculated from the integral ratio of peak ghij and peak a, which is about 51%. As shown by the orange line in Fig. 1 b, the signal at peak g is attributed to the methyl of QA group, and the hydrogen protons at a and f own different chemical shift, which indicate the successful synthesis of QA-PEG.
A four dibenzofuran-terminated hole-transporter, T1DBFBP, realizes high-efficiency and highly stable green TADF OLEDs with an EQE of over 20% and a long operation lifetime LT 50 of 30 000 h at 1000 cd m −2. The article was first published on 30 Nov 2022 Mol. Syst. Des. Eng., 2023, Advance Article https://doi/10.1039/D2ME00225F